Details of Natural Product (NP)

General Information of Natural Product (ID: NP0574)
  Natural Product Name
(+)-Beta-Himachalene Oxide
  Synonyms
(+)-.beta.-Himachalene oxide; 7-Oxatricyclo[6.4.0.0.(6,8)]11-dodecene, 2,2,6,11-tetramethyl, [1R,6S,8R]-; (1aS,5aR,9aR)-1a,5,5,7-Tetramethyl-1a,2,3,4,5,5a,8,9-octahydrobenzo[1,7]cyclohepta[1,2-b]oxirene; Benzo[1,7]cyclohept[1,2-b]oxirene, 1a,2,3,4,5,5a,8,9-octahydro-1a,5,5,7-tetramethyl-, (1aS,5aR,9aR)-; Benzo[1,7]cyclohept[1,2-b]oxirene, 1a,2,3,4,5,5a,8,9-octahydro-1a,5,5,7-tetramethyl-, [1aS-(1a.alpha.,5a.alpha.,9aS*)]-
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  Formula C15H24O
  Weight 220.35
  Structure Could Not Find 2D Structure
3D Structure Download 2D Structure Download
  InChI InChI=1S/C15H24O/c1-11-6-9-15-12(10-11)13(2,3)7-5-8-14(15,4)16-15/h10,12H,5-9H2,1-4H3
  InChI Key FDCRKPAGAMPEAD-UHFFFAOYSA-N
  Isomeric SMILES CC1=CC2C(CCCC3(C2(O3)CC1)C)(C)C
  Canonical SMILES CC1=CC2C(CCCC3(C2(O3)CC1)C)(C)C
  External Links PubChem ID 78409657

 The Content Variation of Natural Product Induced by Different Factor(s)
      Species Name: Pinus sylvestris
  Factor Name: Locality Variation [1]
              Species Info Factor Info
               Experiment Detail
The branches of pine were collected in July, 1996 in 15 different locations in Lithuania in the following regions: Western part (Silute, Jurbarkas, Kursiu Nerija), Eastern part (Salcininkai, Zarasai, Moletai), Southern part (Varena, Trakai, Radviliskis) and central part (Ukmerge, Jonava, Kaisiadorys). The branches in each location were collected from the trees in approximately 1 km radius.
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               Factor Function
More than 70 constituents were identified (64 positively and 10 tentatively) in the oils. alpha-Pinene (18.5-33.0%) and delta-3-carene (9.1-24.6%) were dominating constituents with the only one exception when the germacrene-4-ol content in one of the samples was 13.2%. The important bornyl acetate content varied from 0.5% to 3.0%. The main sesquiterpenes were beta-caryophyllene, germacrene D, bicyclogermacrene, delta-cadinene, gamma-cadinene, germacrene D-4-ol, cubenol (2.0-5.1%) and alpha-cadinol (1.9-7.7%).
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               Factor Part Location NP Content
 
Locality: Jonava, Lithuania
 Branches Jonava, Lithuania
NP Content: 8.5 %
 
Locality: Jurbarkas, Lithuania
 Branches Jurbarkas, Lithuania
NP Content: 5.7 %
 
Locality: Kaisiadorys, Lithuania
 Branches Kaisiadorys, Lithuania
NP Content: 4.9 %
 
Locality: Moletai, Lithuania
 Branches Moletai, Lithuania
NP Content: 5.1 %
 
Locality: Neringa (Smiltyne), Lithuania
 Branches Neringa (Smiltyne), Lithuania
NP Content: 2.6 %
 
Locality: Radviliskis, Lithuania
 Branches Radviliskis, Lithuania
NP Content: 3.6 %
 
Locality: Salacininkai, Lithuania
 Branches Salacininkai, Lithuania
NP Content: 4.1 %
 
Locality: Silute, Lithuania
 Branches Silute, Lithuania
NP Content: 3.1 %
 
Locality: Trakai, Lithuania
 Branches Trakai, Lithuania
NP Content: 8.2 %
 
Locality: Ukmerge, Lithuania
 Branches Ukmerge, Lithuania
NP Content: 3.5 %
 
Locality: Varena, Lithuania
 Branches Varena, Lithuania
NP Content: 3.6 %
 
Locality: Vilnius, Lithuania
 Branches Vilnius, Lithuania
NP Content: 6.1 %
 
Locality: Zarasai, Lithuania
 Branches Zarasai, Lithuania
NP Content: 13.2 %
 
Locality: Zarsai (lmbradas), Lithuania
 Branches Zarsai (lmbradas), Lithuania
NP Content: 13.2 %
 
Locality: Zarasai (Sunele), Lithuania
 Branches Zarasai (Sunele), Lithuania
NP Content: 8.7 %
References
1 Composition of Essential Oils of Pinus sylvestris L. from Different Locations of Lithuania