General Information of Natural Product (ID: NP0629)
  Natural Product Name
Trans-Chrysanthenyl Acetate
  Synonyms
trans-Chrysanthenyl acetate
Click to Show/Hide
  Formula C12H18O2
  Weight 194.27
  Structure Could Not Find 2D Structure
3D Structure Download 2D Structure Download
  InChI InChI=1S/C12H18O2/c1-7-5-6-9-11(14-8(2)13)10(7)12(9,3)4/h5,9-11H,6H2,1-4H3/t9-,10+,11+/m0/s1
  InChI Key UASZOTVHPVEMQR-HBNTYKKESA-N
  Isomeric SMILES CC1=CC[C@H]2[C@H]([C@@H]1C2(C)C)OC(=O)C
  Canonical SMILES CC1=CCC2C(C1C2(C)C)OC(=O)C
  External Links PubChem ID 10899521

 The Content Variation of Natural Product Induced by Different Factor(s)
      Species Name: Bupleurum gibraltarium
  Factor Name: Developmental Stage Variation [1]
              Species Info Factor Info
               Experiment Detail
Plant material: Samples of B. gibraltarium were gathered in November 1995 during the fruiting period (F), in May 1996 during the pre-flowering period (PF), in July 1996 during the full flowering period (FF), and in September 1996 during the late flowering period (LF) from El Zumbel area (UTM: 30SVG3278) . Every sample consisted in the whole aerial parts of five single plants growing wild near one to another. Once the plants reached the laboratory, they were airdried for seven to 15 days, and separated by parts, i.e., leaves, stems, umbel rays and, when present, fruits.
Click to Show/Hide
               Factor Function
In the leaf oils, sabinene (12.0-33.9%) and limonene (7.8-23.4%) were the main components, the sabinene level being minimum in full flowering and maximum in fruiting. In stem oils, sabinene (4.7-21.6%) and 2,3,4-trimethylbenzaldehyde (9.3-13.6%) were the main components, the sabinene level being minimum in pre-flowering and maximum in full flowering. In umbel ray oils, sabinene (20.7-43.1%) was the first component in all the phenological periods, followed by alpha-pinene (7.3-28.2%). Both monoterpenes increased their levels in late flowering and reached minimum amounts in fruiting.
Click to Show/Hide
               Factor Part Location NP Content
 
Leaf: full pre-flowering stage
Leaves Spain
NP Content: 0.7 %
 
Stem: full pre-flowering stage
Stems Spain
NP Content: 0.2 %
 
Aerial part: full flowering stage
Aerial parts Spain
NP Content: 2.8 %
 
Umbel: full flowering stage
Umbels Spain
NP Content: 1.3 %
 
Fruit: full fruiting stage
Fruits Spain
NP Content: 1.9 %
      Species Name: Tanacetum cadmeum ssp. orientale
  Factor Name: Locality Variation [2]
              Species Info Factor Info
               Experiment Detail
Plant materials were collected during the flowering period in July 2002 from the Dumluca Mountain in the vicinity of Divrigi village of Sivas city at 1900 m altitude and Saksagan Gorge in Saimbeyli village of Adana city at 1900 m altitude.
Click to Show/Hide
               Factor Function
The flower, stem and root oils of T. cadmeum ssp. orientale collected from the Adana location were characterized with alpha-thujone (25%, 5.2%), cis-linalool oxide (6.8%, 12.8%), trans-chrysanthenyl acetate (5.8%, 8.5%) for flower and stem oils, and beta-eudesmol (10.3%, 6.2%, 13.8%); in addition, stem oil contained 1,8-cineole (6.6%) and root oil contained hexadecanoic acid (6.0%), spathulenol (5.8%) and beta-muurolol (5.3%). The flower and stem oils of T. cadmeum ssp. orientale collected from the Sivas location were characterized with camphor (25.9%, 14.8%), borneol (15.4%, 25.8%) and alpha-thujone (7.8%, 5.5%); in addition, stem oil contained 1,8-cineole (7.4%) and root oil contained nonacosane (16.2%), spathulenol (6.8%) and hexadecanoic acid (5.8%).
Click to Show/Hide
               Factor Part Location NP Content
 
Flower: (Locality: Adana, Turkey)
Flowers Adana, Turkey
NP Content: 5.8 %
 
Stem: (Locality: Adana, Turkey)
Stems Adana, Turkey
NP Content: 8.5 %
 
Root: (Locality: Adana, Turkey)
Roots Adana, Turkey
NP Content: 2.4 %
References
1 Seasonal Variation of Leaf, Stem and Umbel Ray Essential Oils of Bupleurum gibraltarium Lam.
2 The Variation in the Essential Oil Composition of Tanacetum cadmeum (Boiss.) Heywood ssp. orientale Grierson from Turkey